Quick steps to get Kitserver working with PES 2010:
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1. Copy the game exe (pes2010.exe) and the settings exe (settings.exe) here.
2. Then run kitserver's manager.exe program, select those files, and click 'Attach'.
3. Run kitserver's config.exe program, select the options you want, click 'Save'.
4. Double-click on the game exe in this folder to start the game.